From the Pilot episode the conversation between the Religious Right leaders and WW staffers until the President steps in with one of the greatest entrances in all of TV IMHO
From Great moments in west wing history the moment at the end of season 4 where Zoey is kidnapped and Leo must tell the president. The music is Massive Attack's song Angel
From Great Moments in West Wing History, the fantastic scene where Leo is walking through the west wing and gathering staffers for the senior staff meeting. The beginning of a beautiful show! See the special features on the DVDs for more great fun on this spectacular episode.
From Great Moments in WW History the end of the 1st term and Bartlet nails a solid win over Richie. The touching scene with the First Lady as we begin a new era of Bartlet's White House
From the Greatest Moments in West Wing History we see the explanation of "What's Next." The early days in the campaign where the staff discusses the primary states and the strategy before the convention to make Bartlet competitive against Hoynes. Ep. 2x01
From the Greatest Moments in West Wing History - the scene in the very early days where Bartlet is doing a town hall style meeting in NH and is asked about a tough bill he voted against. Bartlet speaks poetically about children in poverty. Its the moment Josh decides to join the campaign. Episode 2x01